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IEC 60754 (Halogen-free)

IEC 60754 (Halogen-free)

IEC 60754 — proving a cable is truly “halogen-free”

When halogen-containing polymers (PVC, CPE, PTFE) burn they release hydrogen chloride, bromide and fluoride that corrode steel, destroy electronics and endanger people’s lungs.  IEC 60754, Test on gases evolved during combustion of materials from cables, tells laboratories exactly how to measure those acidic gases, so buyers can enforce “low-smoke zero-halogen” (LSZH) claims instead of just trusting a catalogue line. iTeh Standards

IEC 60754

1. Scope and document map

Part Latest consolidated edition What it measures Typical purpose
60754-1 2011 + AMD1:2019 CSV Total halogen acid gas content (mg HCl-equivalent
per g of material)
Raw-material screening, cable component approval
iTeh Standards
60754-2 2011 + AMD1:2019 CSV Acidity (pH) and conductivity of the aqueous
solution that absorbs the combustion gases
Pass/fail criteria used on finished LSZH
cables (pH ≥ 4.3, σ ≤ 10 µS mm-¹)
iTeh Standardsproducts.lappgroup.com
60754-3 2018 Low-level halogen content by ion-chromatography
(Cl, Br, F, I down to ≈ 1 mg/g)
High-accuracy check for premium “HF”
materials or where fluoropolymers are suspected
iTeh StandardsiTeh Standards

All three parts use the same vertical quartz tube furnace to burn a 1 g sample at 800 ± 10 °C; the evolving gases are swept by air or nitrogen into 300 ml of de-ionised water for analysis. 

2. Why 60754 underpins every LSZH spec

IEC 60502 adopts the familiar U<sub>0</sub>/U (Um) format:

3. Inside the test

Step 60754-1 (acid mass) 60754-2 (pH / σ) 60754-3 (ion-chromatography)
Combustion Heat to 800 °C for 20 min; weigh residue to calculate
mg acid/g sample
Identical Identical
Absorption 300 ml water; titrate with 0.1 mol NaOH to
pH 4 → convert to HCl eq.
Measure pH & conductivity directly Same solution retained
Reporting mg HCl-eq / g (HF excluded) pH (≥ 4.3) & σ (≤ 10 µS mm-¹) mg Cl, Br, F, I / g via IC, LOD ≈ 1 mg kg-¹

Note: 60754-1 cannot quantify hydrofluoric acid accurately below 5 mg g-¹, which is why 60754-3 exists for critical optical-fibre or aircraft-wire applications. 

4. Interpretation of results

Halogen-free cable (marketing sense)
Low-halogen cable
PVC or CPE cable

5. Interaction with other fire standards

Question Standard involved Relationship
“Will the cable propagate flame?” IEC 60332 60332 tests flame spread; 60754 says how corrosive the smoke will be.
“How much smoke or heat is produced?” IEC 61034, EN 50399 (cone calorimeter) Combine with 60754 to satisfy EU CPR Euroclasses B2ca-s1a,d1,a1.
“Is the cable still live during fire?” IEC 60331, BS 6387 Circuit-integrity cables (BFOU, FP600S) must meet 60754 if marketed
as LSZH.

6. Materials science: how compounds meet 60754

Halogen-free jackets are polyolefins filled with >60 % aluminium or magnesium hydroxide.  At ≈ 200 °C the filler releases water, diluting flame and producing only trace chloride. Cross-linking (XLPO) or adding siloxane compatibiliser raises mechanical strength that high filler load would otherwise drop.
Designers track two levers:

Well-formulated HFFR compounds routinely hit < 2 mg g-¹ acid, pH ≈ 6.5, σ ≈ 1 µS mm-¹—beating the 60754 lines with margin.

7. Specifier’s quick checklist

7. Industry adoption snapshots

Sector Typical requirement Reason
Data centres 60754-2 + Euroclass B2ca-s1a,d1,a1 Protect copper & servers from acid vapour during fire.
Rail rolling-stock (EN 45545-2 HL3) 60754-2 pH ≥ 4.3; σ ≤ 10 µS mm-¹ Passenger evacuation routes in tunnels.
Offshore rigs (NEK 606 SHF2) Must pass 60754-2 and 60332-3 Cat A Halogen-free smoke crucial for electronic ~survival in enclosed modules.

9. Emerging developments (2025-2028)

10 Key take-aways

Conclusion

Designers, QA managers and procurement teams who understand IEC 60754 can separate marketing hype from proven halogen-free performance—and ensure that when a fire does break out, the smoke is far less toxic and the post-incident cleanup does not involve replacing every corroded relay, server or busbar in the building.